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X-WR-CALNAME;VALUE=TEXT:Alison Fout
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SUMMARY:Alison Fout
DESCRIPTION:<p>	Professor <a title="" href="https://chemistry.illinois.edu/fout" data-url="https://chemistry.illinois.edu/fout">Alison Fout</a> University of Illnois at Urbana-Champaign.  "Ligand influences on base metals for multi-electron transformations."  Woodward CCB Departmental Colloquium.<!--break-->Abstract: </p><p style="text-align: justify;">	<font face="Calibri"><font size="3">Multi-electron transformations featuring base metals are both particularly challenging and interesting. A series multi-dentate ligand frameworks containing both hydrogen bond donating and accepting moieties in the secondary coordination sphere have been synthesized and reactivity will be described. This work will highlight the dynamic bonding of the secondary coordination sphere and its influences on hydroxylation versus hydrogen atom transfer to an organic radical. </font></font></p><p style="text-align: justify;">	<font face="Calibri"><font size="3">The use of an electron-rich bis(carbene) ligand on cobalt to mediate two-electron chemistry will be described. Here we have explored the <em>para</em>hydrogenation of olefins to be used as parahydrogen induced polarization (PHIP) transfer catalyst in </font><sup><font size="2">13</font></sup><font size="3">C NMR spectroscopy and for developing contrast agents in magnetic resonance imaging. </font></font></p><p style="text-align: justify;">	 </p><p>	 </p>
LOCATION:Pfizer Lecture Hall
STATUS:CONFIRMED
DTSTART:20181119T211500Z
DTEND:20181119T221500Z
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